Uv radiations are very harmful and can cause health issues such as skin cancer, ageing. Approximately 90% ozone is present in stratosphere at the height of 10 to 17 kilometer and is called ozone layer while remain ing 10% is present in troposphere 3. Application of ozone in water treatment was performed in 1893 in holland. A brief history of stratospheric ozone research juser. Twenty questions and answers about the ozone layer noaa esrl. Experts blame ozonelayer depletion on manmade chem icals containing chlorine and. This depletion makes humans more vulnerable to the uvb rays which are known to cause skin cancer as well as other genetic deformities. As a result, there has been a general thinning of the ozone layer over most of the globe, including between five to nine per cent depletion over australia since the 1960s. Global climate change, acid rain, ozone depletion filename. For studies of the past ozone behaviour, offline chemistry transport models ctms using observed meteo. Causes of ozone layer depletion and its effects on human. The chemistry of ozone and photochemical smog formation tropospheric ozone and photochemical smog formation. The ozone depletion phenomenon the national academies press. The ozone hole 12 explaining the ozone hole the role of polar stratospheric clouds 14 summary of conditions for the ozone hole 16 iv.
This ozone hole has reappeared at this time each year figure 10. Normal ozone ozone layer depletion and its effects. Ozone layer depletion is one of the major environmental issues which is getting thinner day by day as a. Ozone depletion describes two distinct but related phenomena observed since the late 1970s. A chemistrytransport model simulation of middle atmospheric. Pdf chlorofluorocarbons cfcs and their effect on the atmosphere.
The word theory is used in this context because, we should remember, in the mid and late 1970s the notion of stratospheric ozone depletion was still just that a theory. Introduction ozone depletion due to manmade chlorinated and. Ozone depletion university of california, berkeley. Cfcs have been confirmed as the main cause of ozone depletion in the stratosphere4. The branch of science which deals with the chemical phenomena occuring in the environment is called as environmental chemistry. Download chlorofluorocarbons and ozone depletion book pdf free download link or read online here in pdf. Read online chlorofluorocarbons and ozone depletion book pdf free download link book now. Atmospheric chemistry, school of earth, atmosphere and life sciences, university of wollongong, wollongong, new south wales, australia. Ozone depletion is the process of destruction of the ozone layer which can cause adverse effects on the living forms by many pollutants releases out from the vehicles, industries etc. Ozone depletion potentials and global warming potentials the effectiveness of bromine compared with chlorine on a peratom basis for global ozone depletion, typically referred to as. Ozone depletion and recovery ozone depleting substances greenhouse gases human wellbeing and ecosystem sustainability water security food.
The most prominent reactions are the ho x, no x, and cl radical chain reactions these reactions are termed chain reactions because the ozone destroying radical e. Project report on ozone depletion environmental pollution. The net gwps of halocarbons depend strongly upon the effectiveness of each compound for ozone destruction. It is based on longer observational records, new chemistry. What are the causes and effects of ozone depletion. Department of chemistry and department of earth system science, university of california. These advances add to the scientific basis for decisions made by the parties to the montreal protocol. This is not really a hole through the ozone layer, but rather a large area of the stratosphere with extremely low amounts of ozone. Chapte r ozone depletion potentials, global warming. Ozone layer depletion causes, effects and solutions. Carbon dioxide is the major contributor to global warming.
Let us have a detailed look at the various causes and effects of ozone layer depletion. Ozone in the stratosphere is necessary to life as we know it because it absorbs energetic uv radiation. The thinning is most pronounced in the polar regions, especially over antarctica. Global change instruction program includes bibliographical references and index. Cfcs destroy the ozone in the stratosphere 15 20 km above the earths surface ozone concentrations are measure in dobsen units, 1 dobsen unit represents 1 molecule of o 3 for every 1 billion air molecules ozone loss is greatest over antarctica where the ozone depletion has been recorded and is commonly referred to as the ozone hole. Observations of column abundances of clo 1018 molecules m2 and ozone dobson units above 100 hpa about 16 km in the antarctic in september 1992, from the.
Pdf there are many situations where human activities have significant effects on the environment. Ground ozone concentration is lower in polar and equatorial regions. The effect of super volcanic eruptions on ozone depletion in a chemistry climate model article pdf available in advances in atmospheric sciences 368 july 2019 with 4 reads. These chemicals are found in cleaning agents, aerosols, insulating foam, and refrigerants. From protecting the ozone layer to preventing global warming 1 advent of the ozone layer depletion issue chlorofluorocarbons cfcs do not exist in nature. Ozone layer depletion causes, effects and solutions 7. Stratospheric ozone is formed naturally by chemical reactions involving solar ultraviolet radiation sunlight and oxygen molecules, which make up.
Disposal considerations collect and reclaim or dispose in sealed containers at licensed waste disposal site. The phrase the ozone hole is used to describe the severe annual antarctic springtime ozone depletion that was. Protecting the ozone layer department of the environment. Ozone is harmful at ground level but high up the atmosphere ozone layer plays a vital role in the protection of all living beings. Ozone layer depletion cause, effects, and solutions biology. Ozone depletion is largely a result of manmade substances. The sun propagates ultraviolet radiations which as an adverse effect on living beings. An ozone molecule is made up of three oxygen atoms. Ozone depletion is primarily caused by human activities. The image of stratospheric ozone shows total ozone over antarctica for 6 september 2000, reproduced from ref. Solomon 14, that is most fully throwing light on all questions, connected with chemistry of ozone in the middle atmosphere.
Global warming and ozone layer depletion are two different problems see the sidebar misconceptions about global atmospheric change on page 95. The montreal protocol on substances that deplete the ozone layer came into force in 1989 and, including a number of subsequent amendments, has since been very successful in reducing the production of many of these compounds on a global scale2. The depletion of ozone layer has trickle down effects in the form of global warming, which in turn leads to melting of polar ice, which will lead to rising sea levels and climatic changes around the world. A global thinning of the ozone layer results as ozone rich air from the remaining ozone layer flows into the ozone poor areas. Effects of ozone depletion ozone depletion is affecting the human health and environment negatively, as it allows the penetration of uv radiations to reach the earth. Cl2g 2clg in presence of light effects of ozone depletion. The assessment documents the advances in scientific understanding of ozone depletion. Stratospheric ozone is beneficial to life on earth.
Ozone plays a different role in atmospheric chemistry at different heights in the. Minimum ozone levels in the antarctic decreased steadily throughout the 1990s, and less dramatic decreases have been found above other areas of the world. In fact, the 1995 nobel prize in chemistry was awarded to three scientists who revealed the role of manmade chemicals, chlorofluorocarbons, or cfcs, in the ozone depletion process. Frequently asked questions about the ozone layer ozone. Ozone ozone is a molecule comprised of three oxygen atomsits chemical formula is o 3. Examines the phenomenon of ozone loss and considers its chemistry, causes, and prevention.
Pdf causes of ozone layer depletion and its effects on. Each year since the late 1970s, much of the protective layer of stratospheric ozone above antarctica has disappeared during september, creating what is popularly known as the ozone hole. Global ozone depletion and increase of uv radiation caused. Unlike molecular oxygen o 2, ozone is very reactive in the presence of most other species. Due to human activity 2 compounds no and cfc are responsible for depletion of o 3 layer. In atmospheric chemistry, the activities relate to the different regions of the atmosphere and the different roles that the same chemical can play depending on its location, and the work of atmospheric chemistry. Ozone and uv projections from the chemistry climate model. Ozone layer depletion is one of the major environmental issues which is getting thinner day by day as a result of increasing pollution. Timeline of stratospheric ozone depletion and observations. A discussion of the in situ and remote observations of clo, cloocl, and related species.
Ozone depletion, gradual thinning of earths ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. The most prominent reactions are the ho x, no x, and cl radical chain reactions. The higher ea and low temperatures result in very slow rates. Newly detected ozonedepleting substances in the atmosphere. These radiations can cause severe diseases in humans such as skin cancer, eye damage and genetic mutations etc 9. Additional information on data used for this image is provided by nasa ozone watch 104. Chemistry of ozone depletion fire protection association nz. One example of ozone depletion is the annual ozone hole over antarctica exit that has occurred during the antarctic spring since the early 1980s. Ozone in the troposphere is toxic due to its reactive oxidizing capabilities. The thinning of the ozone layer has increased the risk that australians already face from overexposure to uv radiation from an outdoor lifestyle. The subtropical ground ozone concentration in northern hemisphere is twice the corresponding region in southern hemisphere 5.
On the chain length and rate of ozone depletion in the. The cl free radicals initiate and catalyse a chain reaction capable of breakdown of over 1,00,000 ozone molecules resulting in ozone depletion. Abstract solar ultraviolet radiation creates an ozone layer in the atmosphere which. When there was no ozone layer, life could only exist in the sea.
The global exchange between ozone and oxygen is on the order of 300 million tons per day. Enumerate methods of protecting the ozone layer and preventing its depletion. Ozone in the lower atmosphere contributes to global warming and climate change. Scientific assessment of ozone depletion montreal protocol. Life is protected from uv rays by stratospheric ozone layer which acts as a shield or sun screen 2. During antarctic ozone depletion, heterogeneous chemistry on polar stratospheric clouds pscs is an important reaction. Atmospheric chemistry division at the national center for atmospheric. The role of halogen chemistry in polar stratospheric ozone. Section 3 presents the development of the understand ing of the chemistry of. Pdf the effect of super volcanic eruptions on ozone. Humans have introduced gases and chemicals into the atmosphere that have rapidly depleted the ozone layer in the last century. A paper by research scientists molina and rowland suggested that industrial halocarbons could react in the stratosphere and destroy stratospheric. Chemistry of combustion emissions near the tropopause accent project and is a contributor to the world meteorological organizations quadrennial scientific assessment of ozone depletion reports.
Scientific evidence of ozone depletion the initial hypothesis linking cfcs and depletion of the stratospheric ozone layer was published in 1974. Ozone depletion consists of two related events observed since the late 1970s. The natural distribution of ozone around the earth is. This extreme stability allows cfcs to slowly make their way into the stratosphere most molecules decompose before they can cross into the stratosphere from the troposphere. All books are in clear copy here, and all files are secure so dont worry about it.
An analysis of the laboratory measurements the cloocl cross sections and related quantities as well as the challenges associated with the various studies. O 3 depletion leads to the entry of more uv radiation into the troposphere. Assessment of temperature, trace species, and ozone in. Ozone is good in the stratosphere because it absorbs all of the most energetic ultraviolet radiation uvc, most of the uvb radiation and some of the least energetic uv radiation uva. One of these atoms can react with another oxygen molecule to form an ozone molecule. Ozone layer depletion cause, effects, and solutions. This layer absorbs the radiations and prohibits them from entering the outer surface of the earth. Up to 98% of the suns highenergy ultraviolet light uvb and uvc are absorbed by the destruction and formation of atmospheric ozone. Chapter 15 air pollution and stratospheric ozone depletion. Since that time, its use has spread in europe and the us due to its strong oxidizing properties, ozone is currently known as one of the most efficient and fastest microbicides breaks the cell membrane resulting in.
Estimates of ozone depletion and skin cancer incidence to examine the vienna convention achievements. The chemical and dynamical processes controlling stratospheric ozone are well understood, with ozone depletion being fundamentally driven by the atmo spheric. These compounds are chemically inert and may remain in the atmosphere for 40150 years. List of books and articles about ozone layer online. Air pollution and global warming summary of materials related to university of washington course atm s 458 air pollution chemistry taught autumn 2014 by professor joel thornton compiled by michael c.
He has written more than 50 publications and holds a ph. Most ozone is found in the stratosphere upper part of the atmosphere, more than 10 to 16 kms from the surface of the earth. The first manmade threat to the ozone layer was noted by harold johnston 1971. Here we summarize the salient results of ccmi regarding stratospheric ozone depletion and recovery. The antarctic vortex traps cfcs the low polar temperatures results in ice particles on which gassolid reactions can occur efficiently the same reactions in the gas phase have much higher activation energies. The most prominent manifestation of stratospheric ozone depletion is the antarctic ozone hole. Stratospheric ozone depletion, ultraviolet radiation and health. O 3 reacts readily with radical species compounds with unpaired electrons and compounds containing double bonds. In the troposphere, ozone is formed by a different set of chemical reactions that involve. The questions and answers format divides the narrative into topics that. This was also the start of intensive research into the chemistry of the atmosphere. On the role of heterogeneous chemistry in ozone depletion.
The main effect of ozone depletion is an increase in uvb rays reaching the earths surface causes. Montreal protocol and subsequent treaties ban world. The link between climate change and stratospheric ozone depletion is usually studied using models. The role of halogen chemistry in polar stratospheric ozone depletion section 1. Download a pdf of stratospheric ozone depletion by halocarbons by the national research council for free. How severe is the depletion of the antarctic ozone layer. Due to its environmental significance, the chemistry of atmospheric ozone and ozone depletion has been a subject of much research and discussion. Like an infection that grows more and more virulent, the continentsize hole in earths ozone layer keeps getting bigger and bigger. Montreal protocol on substances that deplete the ozone layer.
Chlorofluorocarbons or cfcs also wellknown as freon are. Mar 21, 2020 ozone depletion, gradual thinning of earths ozone layer in the upper atmosphere caused by the release of chemical compounds containing gaseous chlorine or bromine from industry and other human activities. The emission of ozonedepleting gases impacted the earths ozone layer a. Besides carbon dioxide, other greenhouse gases are methane, water vapour, nitrous oxide, cfcs and ozone.
In addition to uv absorption and oxygen radical reaction see chapman reactions, ozone can be destroyed by combination with other radical species. Environmental chemistry 401 carbon dioxide crosses the delicate proportion of 0. The above reaction leads to the formation of chlorine and begins a chain reaction thereby causing ozone depletion. The chlorofluorocarbon and the halons are potent ozone depletors.
This study was conducted at university of gujrat during 20142015 as a term paper for master of philosophy. The simulation of the antarctic ozone hole by chemistry. Other adverse effects no other adverse environmental effects e. Ozone depletion is not limited to the area over the south pole. Find answers to frequently asked questions about the ozone layer, ozone depletion, and the effects of ozone depletion on health and the environment. The montreal protocol 1 deals with substances that deplete the ozone layer ods and how to reduce them. Gwps including indirect effects of ozone depletion have been estimated fo r a variety of halocarbons cfcs, halons, hcfcs, etc. Depletion of stratospheric ozone o3, as commonly known as the hole in the ozone layer, is an issue of international concern. Ozone depletion, ultraviolet radiation, climate change and. In 1985 the british antarctic survey reported a startlingly large depletion of ozone in september and october, at the end of the antarctic winter. Ozone layer depletion ozone layer depletion is the gradual thinning of the earths ozone layer in the upper atmosphere caused due tho release of chemical compounds containing gaseous bromine or chlorine from industries or other human activities. Most questions and answers are updates of those presented in previous ozone assessments, while others have been added or. Global warming is caused by the greenhouse effect, which is essential to life as we know it on planet earth. In contrast, eruptions increased ozone loss rates over the depletion era from 1980 to 1998.
Cfc molecules are made up of chlorine, fluorine and carbon atoms and are extremely stable. Atmospheric chemistry, chemical r eactions, and history. Pdf download files stratospheric ozone depletion, ultraviolet radiation and health pdf 107kb pdf files for other chapters and for the complete summary. Basic ozone layer science ozone layer protection us epa.
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